A high-resolution analyser for the measurement of ammonium in oligotrophic seawater     

Samer K. Abi Kaed Bey  Douglas P. Connelly  François-Eric Legiret  Andy J. K. Harris  Matthew C. Mowlem 《Ocean Dynamics》2011,61(10):1555-1565

In this work, we describe a high-resolution fluorometric shipboard analyser and an improved method to determine NH₄⁺ in oligotrophic seawater. The limit of detection is <5 nM, calculated with 95% confidence level using the weighted regression line applied to the standard addition method using real samples prepared with low nutrient seawater from the Atlantic. The results are summarised and cross-compared with spiked artificial seawater (ASW) and spiked Milli-Q water samples. The analyser has a precision of ±1–4% with a high performance over a wide range from 5 nM to 25 μM. The methodology of NH₄⁺ analysis is based on the fluorescent product formed between o-pthaldialdehyde and NH₄⁺ in the presence of sulfite. Due to the high resolution of the developed system, we were able to study in depth the sensitivity of the method to salinity, amines, amino acids and potential interferences from particles/algae. The method was found to be sensitive to salinity variations, reducing the signal by up to 85% at 5 nM; this effect decreased at higher concentrations of ammonium. It was noted that the interference from amines at low concentrations was negligible; however, at either high amino acid or high amine concentrations, the signal was depressed. To test for the effect of particles on the system, the system was tested with samples containing phytoplankton (Dunaliella primolecta) cells at different concentrations prepared with ASW to simulate the effect of a phytoplankton bloom. This experiment assessed the potential impact of both particles and other potential fluorescence interferences from cells and/or ammonium leaching from cells. This experiment showed that a phytoplankton bloom could potentially have an impact of up to 12% on the signal of interest. Thus, we propose that this method is suitable for oligotrophic environments rather than coastal and eutrophic environments. The reagent was found to be stable for 17 days and standards of 1 μM were stable for 6 days under laboratory conditions. The developed analyser was successfully demonstrated in the North Atlantic Ocean, in an area of oligotrophic, low NH₄⁺ oceanic waters.  相似文献   

A 500 yr speleothem-derived reconstruction of late autumn–winter precipitation, northeast Turkey     

Catherine N. Jex  Andy Baker  Jonathan M. Eden  Warren J. Eastwood  Ian J. Fairchild  Melanie J. Leng  Louise Thomas  Hilary J. Sloane 《Quaternary Research》2011,75(3):399-405

A verified instrumental calibration of annually resolved δ¹⁸O for a stalagmite from Gümü?hane in northeast Turkey is presented and cross-validated using a ‘leave-one-out’ technique. The amount of late autumn to winter precipitation is negatively correlated with stalagmite δ¹⁸O between AD 1938 and 2004. The observed relationship is extrapolated back to ~ AD 1500 leading to the first long winter precipitation reconstruction for this region. Modern day October to January precipitation is linked to pressure fields in Western Russia. Anomalously lower reconstructed rainfall is recorded in AD 1540–1560 at which time higher pressure over the Caspian Sea region is inferred.  相似文献   

Is silt the most influential soil grain size fraction?     

S.A. Parry  M.E. Hodson  E.H. Oelkers  S.J. Kemp 《Applied Geochemistry》2011

The contribution of individual grain size fractions (2000–500, 500–250, 250–63, 63–2 and < 2 μm) to bulk soil surface area and reactivity is discussed with reference to mineralogical and oxalate and dithionite extractions data. The 63–2 μm fraction contributed up to 56% and 67% of bulk soil volume and BET surface area, respectively. Consideration of these observations and the mineralogy of this fraction suggest that the 63–2 μm fraction may be the most influential for the release of elements via mineral dissolution in the bulk soil.  相似文献   

Soil pH governs production rate of calcium carbonate secreted by the earthworm Lumbricus terrestris     

D.C. Lambkin  K.H. Gwilliam  C. Layton  M.G. Canti  T.G. Piearce  M.E. Hodson 《Applied Geochemistry》2011

Lumbricus terrestris earthworms exposed to 11 soils of contrasting properties produced, on average, 0.8 ± 0.1 mg_CaCO3 earthworm^?1 day^?1 in the form of granules up to 2 mm in diameter. Production rate increased with soil pH (r² = 0.68, p < 0.01). Earthworms could be a significant source of calcite in soils.  相似文献   

Ecosystem-based marine spatial management: Review of concepts, policies, tools, and critical issues   总被引：1，自引：0，他引：1  

Stelios Katsanevakis  Vanessa Stelzenmüller  Andy South  Thomas Kirk Sørensen  Peter J.S. Jones  Sandy Kerr  Fabio Badalamenti  Christos Anagnostou  Patricia Breen  Guillem Chust  Giovanni D’Anna  Mike Duijn  Tatiana Filatova  Fabio Fiorentino  Helena Hulsman  Kate Johnson  Aristomenis P. Karageorgis  Ingrid Kröncke  Simone Mirto  Carlo Pipitone  Susan Portelli  Wanfei Qiu  Henning Reiss  Dimitris Sakellariou  Maria Salomidi  Luc van Hoof  Vassiliki Vassilopoulou  Tomás Vega Fernández  Sandra Vöge  Anke Weber  Argyro Zenetos  Remment ter Hofstede 《Ocean & Coastal Management》2011,54(11):807-820

Conventional sectoral management and piecemeal governance are considered less and less appropriate in pursuit of sustainable development. Ecosystem based marine spatial management (EB-MSM) is an approach that recognizes the full array of interactions within an ecosystem, including human uses, rather than considering single issues, species, or ecosystem services in isolation. Marine spatial planning and ocean zoning are emerging concepts that can support EB-MSM. EB-MSM is driven by high-level goals that managers aim to achieve through the implementation of measures. High-level goals and objectives need to be translated into more operational objectives before specific targets, limits and measures can be elaborated.Monitoring, evaluation and adaptation are necessary to ensure that marine management measures are both effective and efficient. Solid monitoring frameworks are the foundation of adaptive management, as they provide the necessary information to evaluate performance and the effectiveness of management actions. Marine protected areas (MPAs) - possibly set up in networks - constitute a key component in EB-MSM policies and practises and have been applied as a cornerstone in conservation of marine biodiversity, management of fish populations, development of coastal tourism, etc. Moreover, MPA experiences have provided methods and concepts (such as zoning) to a wider EB-MSM context. The assignment of values to biophysical features of the marine environment allows the direct assessment of related management choices and may assist EB-MSM.A range of monetary valuation techniques have been proposed to reduce attributes of goods and services to a single metric. However, in the marine environment such an approach is often over simplistic, and thus less reductive techniques may be necessary. Rather than producing a single metric, the results of non-monetary assessments guide policy allowing weight to be given as necessary to potential areas of conflict and consensus.Strategies to take into account climate change effects and geohazard risks in EB-MSM have been applied or proposed worldwide. EB-MSM regimes must be alert to such risks and flexible to account for changes.  相似文献   

The importance of health co-benefits in macroeconomic assessments of UK Greenhouse Gas emission reduction strategies     

Henning Tarp Jensen  Marcus R. Keogh-Brown  Richard D. Smith  Zaid Chalabi  Alan D. Dangour  Mike Davies  Phil Edwards  Tara Garnett  Moshe Givoni  Ulla Griffiths  Ian Hamilton  James Jarrett  Ian Roberts  Paul Wilkinson  James Woodcock  Andy Haines 《Climatic change》2013,119(2):223-237

We employ a single-country dynamically-recursive Computable General Equilibrium model to make health-focussed macroeconomic assessments of three contingent UK Greenhouse Gas (GHG) mitigation strategies, designed to achieve 2030 emission targets as suggested by the UK Committee on Climate Change. In contrast to previous assessment studies, our main focus is on health co-benefits additional to those from reduced local air pollution. We employ a conservative cost-effectiveness methodology with a zero net cost threshold. Our urban transport strategy (with cleaner vehicles and increased active travel) brings important health co-benefits and is likely to be strongly cost-effective; our food and agriculture strategy (based on abatement technologies and reduction in livestock production) brings worthwhile health co-benefits, but is unlikely to eliminate net costs unless new technological measures are included; our household energy efficiency strategy is likely to breakeven only over the long term after the investment programme has ceased (beyond our 20 year time horizon). We conclude that UK policy makers will, most likely, have to adopt elements which involve initial net societal costs in order to achieve future emission targets and longer-term benefits from GHG reduction. Cost-effectiveness of GHG strategies is likely to require technological mitigation interventions and/or demand-constraining interventions with important health co-benefits and other efficiency-enhancing policies that promote internalization of externalities. Health co-benefits can play a crucial role in bringing down net costs, but our results also suggest the need for adopting holistic assessment methodologies which give proper consideration to welfare-improving health co-benefits with potentially negative economic repercussions (such as increased longevity).  相似文献   

Climate change impacts on global agriculture   总被引：1，自引：0，他引：1  

Alvaro Calzadilla  Katrin Rehdanz  Richard Betts  Pete Falloon  Andy Wiltshire  Richard S. J. Tol 《Climatic change》2013,120(1-2):357-374

Based on predicted changes in the magnitude and distribution of global precipitation, temperature and river flow under the IPCC SRES A1B and A2 scenarios, this study assesses the potential impacts of climate change and CO₂ fertilization on global agriculture. The analysis uses the new version of the GTAP-W model, which distinguishes between rainfed and irrigated agriculture and implements water as an explicit factor of production for irrigated agriculture. Future climate change is likely to modify regional water endowments and soil moisture. As a consequence, the distribution of harvested land will change, modifying production and international trade patterns. The results suggest that a partial analysis of the main factors through which climate change will affect agricultural productivity provide a false appreciation of the nature of changes likely to occur. Our results show that global food production, welfare and GDP fall in the two time periods and SRES scenarios. Higher food prices are expected. No matter which SRES scenario is preferred, we find that the expected losses in welfare are significant. These losses are slightly larger under the SRES A2 scenario for the 2020s and under the SRES A1B scenario for the 2050s. The results show that national welfare is influenced both by regional climate change and climate-induced changes in competitiveness.  相似文献   

Fisheries and failing states: The case of Sierra Leone     

Andy Thorpe  David Whitmarsh  Ernest Ndomahina  Andrew Baio  Miatta Kemokai  Thomas Lebbie 《Marine Policy》2009

Marine fisheries play an important role in the economy of Sierra Leone, supporting livelihoods and contributing significantly to food security. This paper looks in detail at how the performance of fisheries was impacted by the ten year civil war, an event which contributed to the country's reputation for being a “failed state”. The paper focuses mainly on the artisanal fisheries sector, which employs the majority of the country's coastal population, and demonstrates how the conflict caused major social dislocation to fishing communities as well as reducing the productive capacity of the fleet. The paper concludes with a discussion of the policy challenges now facing Sierra Leone, particularly the prevention of resource looting through illegal fishing of the offshore stocks and the development of strategies to enable the potential wealth of these fisheries to be captured.  相似文献   

Spectrophotometric discrimination of river dissolved organic matter     

Andy Baker 《水文研究》2002,16(16):3203-3213

There is a need to be able to differentiate the dissolved organic matter (DOM) fraction in river waters. Research in the 1970s and 1980s has attempted to utilize both absorbance and fluorescence to distinguish between DOM fractions in river waters, but both were limited by the available technology. Total organic carbon content has, therefore, been widely used as a standard method of measuring DOM concentration, although it has little power to differentiate DOM fractions. Recent advances in fluorescence spectrophotometry enable rapid and optically precise analysis of DOM. Here, we show how a combination of both fluorescence and absorbance can be used to discriminate statistically between spatial variations of DOM in tributaries in a small catchment of the Ouseburn, NE England. The results of the discriminant analysis suggest that about 70% of the samples can be correctly classified to its tributary. Discriminant function 1 explains 60·8% of the variance in the data and the fulvic‐like fluorescence intensity has the largest absolute correlation within this function; discriminant function 2 explains a further 21·5% of the variance and the fulvic‐like fluorescence emission wavelength has the largest absolute correlation within this function. The discriminant analysis does not correctly classify all tributaries every time, and successfully discriminates between the different tributaries 70% of the time. Occasions when the tributary waters are less well discriminated are due to either episodic pollution events (at two sites) or due to tributaries that have strong seasonal trends in spectrophotometric parameters, which allows the sites to be misclassified. Results suggest that spectrophotometric techniques have considerable potential in the discrimination of DOM in rivers. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Modelling the Transport and Export of Sediments in Macrotidal Estuaries with Eroding Salt Marsh     

Xiaorong Li  Andy Plater  Nicoletta Leonardi 《Estuaries and Coasts》2018,41(6):1551-1564

A process-based numerical model is applied to investigate sediment transport dynamics and sediment budget in tide-dominated estuaries under different salt marsh erosion scenarios. Using a typical funnel-shaped estuary (Ribble Estuary, UK) as a study site, it is found that the remobilization of sediments within the estuary is increased as a result of the tidal inundation of the eroded salt marsh. The landward export of the finest sediment is also intensified. The relationship between salt marsh erosion and net landward export of sediments has been found to be non-linear—with the first 30% salt marsh erosion causing most of the predicted export. The presence of vegetation also influences the sediment budget. Results suggest that vegetation reduces the amount of sediment being transported upstream. Again, the trapping effect of salt marsh in terms of plant density is non-linear. Whilst a vegetated surface with a stem density of 64 plants/m² decreased the net landward export of very fine sand by around 50%, a further increase in stem density from 64 to 512 plants/m² had a relatively small effect.  相似文献